Heterotrinükleer geçiş metalleri komplekslerinin hazırlanması ve yapılarının incelenmesi
Özet
In this study, an ONNO type N,N'-bissaIicylidene-l,3 diminopropane Iigand has been synthesized. Previous studies some homotrinuclear complexes of Ni-Ni-Ni, Cu-Cu-Cu, Zn-Zn-Zn, Cd-Cd-Cd nucleus structured and u-bridged linear type complexes have been prepared using this Iigand. In this study realization that the +2 charged central ion of the three ions could be a different ion, has led to the synthesis of many heteronuclear complexes like Ni-Cu-Ni, Ni-Co-Ni, Ni-Cd-Ni, Cu-Cd-Cu and Cu-Mn-Cu. The structures of the heteronuclear complexes were studied using IR spectroscopy, TGA analysis, element analysis and X-ray diffraction.Key Words : Schiff base, heterotrinuclear complexes.polynuclear complexes,TGA