N-Diklorofosforil-P-trikloromonofosfazen alkoliz ve aminoliz reaksiyonlarından oluşan ürünlerin yapılarının incelenmesi

Abstract

IV ABSTRACT Masters Thesis AMINOLYSIS AND ALCOHOLYSIS OF P-TRICHLORO-N-DICHLORO PHOSPHORYLMONOPHOSPHAZENE AND THE İNVESTİGATİOUS OF THE STRUCTURES OF PRODCTS Hakan DAL Ankara University Graduate School of Natural and Applied Sciences Deparment of Chemistry Supervisor: ProfDr.Zeynel KILIÇ 1997, Page: 48 Jury: ProfDr.Zeynel KILIÇ1997 Prof Dr. Gürol OKAY AssocProf Dr. Orhan ATAKOL In this study,l~(dichIoro)phosphinyI-2,2,2-trichloro phosphazene C12P(0)N=PC13 (1) was prepared from phosphorouspentachloride and ammonium sulfate. The substitution reactions of l-(dichloro)phosphinyl-2,2,2- trichlorophosphazene C12P(0)N=PC13 (1) with an excees of primary amines ( t- butylamine) and secondary amines (piperidine and diisopropylamine) in acetonitrile have been investigated. The reactions of compound (1) with t-butylamine, piperidine and diisopropylamine in acetonitrile gave three acylic phosphazanes and four phosphinoylamines. The structures of these compounds have been determined by elemantal analaysis, IR, *H-, 1SC- ve MP-NMR spectral data. The structure of 1-dichloro phosphinoyl-2,2, dichIoro-2-diisopropylaminophosphazane was also determined by X- ray crytallographic data. KEY WORDS: Acyclic Phosphazene Derivatives, Phosphinoyl Amine Derivatives, X-ray Crystallographic Data, Spectroscopic Data