C17H16N2O2Ni.H2O (N,N'-bis-disalisiliden Ni (II) bileşiğinin kristal yapısının çözümlenmesi

Abstract

Masters Thesis Crystal Structure Determination of C17HiqN202Nİ.H20 N,N'-Bis-di salycilidene-(l,3)-propan diamine-Nickel (II) complex Mehmet Kabak Ankara University Graduate School of Natural and Applied Sciences Supervisor: Assoc. Prof.Dr. Yalçın Elerman 1992, Page:64 Jury: Prof. Dr. Engin KENDİ Assoc. Prof. Dr. Yalçın ELERMAN Assoc. Prof. Dr. Çelik TARIMCI In the present study the crystal structure of G\iH\qN202Nİ.H<20 has been investigated. Coordinates of the crystal atoms were found by using di rect method. Obtained atomic coordinates and thermal vibration tensors were refined by means of least-squares technique. The atomic coordinates, bond dis tances, bond angles and atomic planes which are created by these atoms were calculated. As a result of the study, the coordination type of nickel was found. The results were also compared with those of other Schiff base complexes. KEYWORDS rWeissenberg method, least-squares, dihedral angle, bond length, bond angle.