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dc.contributor.authorAtakol, Orhan
dc.date.accessioned2020-02-14T08:49:48Z
dc.date.available2020-02-14T08:49:48Z
dc.date.issued2008
dc.identifier.urihttps://doi.org/10.1107/S1600536807067724tr_TR
dc.identifier.urihttps://dspace.ankara.edu.tr/xmlui/handle/123456789/69508
dc.description.abstractThe crystal structure of the title compound, [Ni2Cd(C17H16- N2O2)2(C2H3O2)2(C3H7NO)2], contains discrete centrosymmetric hetero-trinuclear molecules in which Ni/Cd atom pairs are triply bridged via O atoms from the SALPD2 [N,N0 - bis(salicylidene)-1,3-propanediaminate] and acetate ligands. The central CdII ion is in a distorted octahedral coordination environment formed by four O atoms from two SALPD2 ligands in the equatorial plane and two O atoms of two symmetry-related acetate ligands in the axial positions. The symmetry-related NiII ions are in slightly distorted octahedral environments, coordinated by two O and two N atoms from tetradendate SALPD2 ligands in the equatorial plane, while the axial positions are occupied by O atoms from a dimethylformamide and an acetate ligand. This results in the formation of three edge-shared octahedra in which the NiCd distance is 3.1482 (15) A˚ . The crystal structure is stabilized by weak C—HO hydrogen bonds.tr_TR
dc.language.isoentr_TR
dc.relation.isversionof10.1107/S1600536807067724tr_TR
dc.rightsCC0 1.0 Universal*
dc.rights.urihttp://creativecommons.org/publicdomain/zero/1.0/*
dc.subjectmean (C–C) = 0.019 A˚tr_TR
dc.subjectdata-to-parameter ratio = 12.6tr_TR
dc.titleDi-l2-acetato-1:2j2 O:O0;2:3j2 O:O0-bis- (N,N0-dimethylformamide)-1jO,3jObis{l2-2,20-[propane-1,3-diylbis(iminomethylene)]diphenolato-1j4 O,N,N0 ,O0:- 2j2 O,O0;2j2 O,O0:3j4 O,N,N0 ,O0-1,3- dinickel(II)-2-cadmium(II)tr_TR
dc.typeArticletr_TR
dc.relation.journalActa Crystallographica Bölüm E: Çevrimiçi Yapı Raporlarıtr_TR
dc.contributor.departmentFen Fakültesitr_TR
dc.contributor.authorID7005181405tr_TR
dc.identifier.volume64tr_TR
dc.identifier.issue2tr_TR
dc.identifier.startpage291tr_TR
dc.identifier.endpage292tr_TR
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıtr_TR
dc.identifier.issn/e-issn1600-5368


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