Crystal Structure of Bis[4-(5-methyl-2-oxyphenyl-κO,2κO)-4-imino-2-penten-2-olato-O, O′,N′]copper(II)

Atakol, OrhanYılmaz, Nazife2020-02-152020-02-15199713https://doi.org/10.2116/analsci.13.1051http://hdl.handle.net/20.500.12575/69583The title compound, Cu2(C12H13N02)2, is a doubly oxygen-bridged dimeric copper(II) complex. Doubly oxygen bridged complexes with subnormal magnetic moments are known to exhibit super exchange interaction.l-3 The Cu atoms have a distorted square-planar environment, with bond angles in the range 76.9(1) - 100.3(1)° . The average Cu-0 distance is 1.916(2) A and the average Cu-N distance is 1.941(3) A. The Cu l and Cu2 atoms are located 0.0339(5) and 0.0336(5) A off the coordination best plane, respectively. The bridging angles Cu 1-O 1-Cu2, O 1-Cu2-03, Cu 1-03-Cu2 and 01-Cut-03 are 102.8(1), 76.9(1), 102.5(1) and 77.5(1)°enCC0 1.0 UniversalCrystal Structure of Bis[4-(5-methyl-2-oxyphenyl-κO,2κO)-4-imino-2-penten-2-olato-O, O′,N′]copper(II)Article6105110521348-224609106340