A linear homotrinuclear nickel(II) complex with a reduced ONNO-type Schiff base
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2005
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Abstract
The structure of the title compound, [mu]-formato-bis{[mu]-N,N'-bis[1-(2-oxidophenyl)ethyl]-2-hydroxy-1,3-propanediamine}bis[(N,N-dimethylformamide)nickel(II)] N,N-dimethylformamide disolvate, [Ni3(CHO2)2(C19H24N2O3)2(C3H7NO)2]·2C3H7NO, comprises a centrosymmetric linear homotrinuclear nickel(II) complex. The central and terminal nickel(II) atoms have distorted octahedral coordination geometries.
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Single-crystal X-ray study, .007 A˚ R factor = 0.050, wR factor = 0.129, Data-to-parameter ratio = 18.3